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Trans. Nonferrous Met. Soc. China 25(2015) 850−855
Effects of Co and Al addition on martensitic transformation and
microstructure in ZrCu-based shape memory alloys
Wei-hong GAO, Xiang-long MENG, Wei CAI, Lian-cheng ZHAO
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Received 21 March 2014; accepted 24 July 2014
Abstract: The effect of ternary alloying element Al and quaternary alloying element Co on the martensitic transformation of
ZrCu-based shape memory alloy was investigated. The results show that the addition of Al and Co in ZrCu alloy decreases both the
martensitic transformation temperature and the martensitic transformation temperature hysteresis. Transmission electron microscope
(TEM) observations reveal that the Cm martensite structure is the preferential formation phase. The intervariant structures in
ZrCuAlCo alloy are (021) type I twins, while the dominant substructures inside the martensite variant are the (001) compound twins.
With the increase of Co content, tensile fracture strength and strain are improved obviously.
Key words: ZrCu-based alloy; shape memory alloy; martensitic transformation; microstructure
However, it is not clear that how the addition of different
1 Introduction alloying elements to ZrCu is linked with the martensitic
transformation and the microstructure [13−18].
ZrCu-based shape memory alloys (SEA) have In the present work, the influences of
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