Ta元素的添加对7715D钛合金力学性能的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 22(2012) 510−515 Effect of Re element on oxidation resistance of Ni Al−Mo based alloys at 1150 °C 3 CHENG Yang, ZHANG Heng, SONG Li-wen, MA Yue, LI Shu-suo, GONG Sheng-kai School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191, China Received 9 September 2011; accepted 18 January 2012 Abstract: The isothermal oxidation behaviors of three kinds of Ni Al−Mo based alloys at 1150 °C were studied. The morphology, 3 structure and element distribution of oxide scales of the alloys were researched by scanning electron microscopy, X-ray diffraction and electron probe microanalysis. The research results show that there are three oxide layers, an outer layer of NiO, an intermediate layer mainly composed of NiO, NiAl O and a small amount of NiMoO , and an inner layer of NiAl O and Al O . Re element was 2 4 4 2 4 2 3 mainly distributed in the intermediate layer, which plays a role as “diffusion barrier” in the process of oxidation, and effectively reduces the diffusion rate of Al and Mo elements outward and diffusion rate of O element inward. As a result, a Al-rich oxide layer formed in the inner layer inhibits the growth of oxide layer and improves the oxidation resistance of the alloy. Key words: Ni Al−Mo based alloy; Re element; isothermal oxidation 3