DOPO衍生物阻燃性能研究.pdfVIP

DO O 陶志强 丁佳培 宋 涛 杨士勇 (, , 100190) DO O 及其衍生物具有高效阻燃低烟低毒排放的特点, 可 作为环氧树脂的阻燃剂使用本 文研究了两种含 DO O结构的硅氧烷对环氧树脂阻燃性能的影响结果表明, 引入含磷硅氧烷后环氧树脂的 热稳定性和阻燃性能都有明显的提高在磷含量达到 2%时, 环氧树脂的LOI为 32- 33, 可达到 UL94V - 0级 阻燃标准引入硅烷链段可 通过磷硅协同效应进 一步改善环氧树脂的阻燃性能 DO O, 环氧树脂, 阻燃, 热稳定性 Research on Flame Retardancy of DO O Derivative Tao Zhiqiang Ding Jiapei Song Tao Yang Shiyong ( Laboratory of Advanced olymerM aterials, Institute of Chem istry, Ch inese Academy of Sciences, Beijing 100190) Abstract hosphorus-containing organic compounds such as DO O have several advantages including high flam e-retardant efficiency, low production of corrosive and toxic gases in flames etc. In this work, a novel DO O- based siloxaneswere evaluated as halogen-free flame retardants for epoxy resins. The cured epoxy resins exhibited bet- ter thermal stabilities and greatly mi proved flame retardant properties due to the presence of phosphorus-containing s-i loxanes. The cured epoxy resinsw ith phosphorus loading of 2. 0 wt% showed LOI values of 32- 33 and achieved UL94 V- 0 ratings. Silicon and phosphorus demonstrated a synergistic effect in the flame retarding behavior of the resins. Key words DO O, Epoxy resin, Flame retardancy, Thermal stability 0 O- DMD , 1) , , , 9, 10- - 9- - 10- - 10- ( DO O), , [ 1] , DO O , 1 , [ 2- 4] Fig. 1 Chem ical structure of phosphorus-containing siloxanes 1 DO O 1. 1 , CNE( 195LL), , , ; N ( TD - TGALOI, 21