TiD1.92热解析的动力学行为研究.pdfVIP

V ol No A tomic Energy Science and T echnology M ar TiD 192 T iD T iD T iD T iD kJ mol kJ mol T iD O A doi zk y Kinetics Study of Thermal Decomposition of TiD 192 WA N G Haif eng PEN G Shuming L ON G Xing ui Z HO U Xiaosong LIA N G Jianhua g I ns titute of N uclear Phys ics and Chemis try China A cademy of Eng inee r ing Phys ics M iany ang China Abstract T he thermal decompo sition of T iD ow der to titanium w as investigated by p means of thermal analy sis and theoretical calculation T he model that considers bulk and surf ace processes during desorption show s three kinds of peak in the spectrum T hey are all related to phase transf ormation T he calculated spectrum of spheres particle model is diff erent f rom the spectrum of planar particle model f or their diff erent diff usion models T he decompo sition behavior of T iD by thermal analy sis is consist w ith the result of planar particle model the rate controlling process in T i and T i is the reaction be tw een hy drogen atom s to f orm gaseous molecules on the surf ace and the rate control ling process of decomposition during transf orm is the deuterium diff usion in T i A rrhenius plot s of ex periment data give kJ mol of the surf ace reaction activation and kJ mol of the deuterium diff usion activation in T i Key words T iD thermal analy sis kinetics hase transf ormation diff usion