BN前驱体的制备及碳纤维表面硼氮化.docVIP

BN前驱体的制备及碳纤维表面硼氮化 学 院：化学与环境工程学院 学生姓名： 胡光莹 专业班级：化学工程与工艺0201班 指导老师：袁颂东副教授 Synthesis of the BN Precursor and BN–film on the Carbon fiber Surface [摘要] 硼酸三甲酯目前主要用于有机硼化物的合成及高纯硼的制备，以及作润滑油的减磨,抗磨添加剂等。本文制备采用硼酸和甲醇为原料在60℃制备硼酸甲酯；以及十水硼砂与甲醇反应制备硼酸甲酯。氮化硼是一种有着多种优良性能的无机材料，在很多领域中得到了广泛的应用。本实验采用化学气相沉积法（CVD）合成BN纳米球体。碳纤维由于具有优异的力学和电学性能，被广泛应用于航空、航天、核工业等高科技领域 。但是碳纤维表面惰性大、反应活性低，与基体的粘结性差，影响了复合材料的力学性能，限制了碳纤维高性能的发挥。本实验采用在高温条件下对碳纤维表面硼氮化的方法来改善碳纤维的表面性质，通过多组对比实验发现在700℃下经过氧化后的碳纤维表面硼氮化的效果比较好。 [关键词]：BN ；前驱体 ；硼酸三甲酯 ；碳纤维 ；硼氮化 Abstract The trimethyl borate precursor is used to prepare the organic boric compounds and high pure quality boron and BN. BN is a good lubricating oil additive which can reduce attrition and have Anti-wearing property. In the paper the trimethyl borate in 60℃ is prepared with Boric acid and methyl alcohol , or with ten water borax dehydrate and methyl alcohol. Boron nitride is a kind of inorganic material with various good characteristics, and gets an extensive application in various fields. Chemistry vapor deposition method (CVD) is adopted to synthesize the nano BN sphere. In the other hand, the carbon fiber has the outstanding mechanics and the electricity performance so that it is widely applied in the aviation, astronautics, the nuclear industry and so on. But the carbon fiber surface is inertia because it’s surface energy and response activeness are low. Those lead to difficulty while cohering with the substrate, and limit the application of carbon fiber compound materials and the carbon fiber high performance display. To improve the surface consistent character of carbon fiber with the substrate, in this experiment a treatment of BN film is given on the carbon fiber surface in high temperature condition .Through parallel experiments, the result is found best while preparing BN-film on the surface of oxidated carbon fiber at 700℃. Key word : BN ，Precursor ，Trimethyl Borate ，Carbon fiber ，Boron nitriding 1 内容简介 近年来对氮化硼前驱体的合成研究主要是朝着低耗、高产的经济型的方向发展化，其