GCMS 法快速分析鱼塘水中的硫丹.pdfVIP

刑事技术 2015 年 第40 卷 第 1 期 ·论  著· DOI: 10.16467/j.1008-3650.2015.01.010 GC/MS 法快速分析鱼塘水中的硫丹 1 2 1 徐仿敏 ，李海波 ，刘凌云 （1. 江苏省江阴市公安局，江苏 江阴 214400 ；2. 江苏省常州市公安局，江苏 常州 213000） A Rapid Method for Analysis of Endosulfan in Poisoned Fish Pond Water with GC-MS 1 2 1 XU Fang-min , LI Hai-bo , LIU Ling-yun (1. Jiangyin Public Security Bureau, Jiangyin Jiangsu 214400, China; 2. Changzhou Public Security Bureau, Changzhou Jiangsu 214400, China) ABSTRACT: Objective Endosulfan has been often used to poison fish pond water in Jiangyin city. As the concentration of endosulfan in poisoned water is very low, it is revry difficult to detect endosulfan from water. In this paper, a new simple and rapid method for analysis of endosulfan in poisonedfish pond water was presented. Methods The dispersive liquid-liquid micro-extraction technique (DLLME) coupled with gas chromatography-ion trap mass spectrometric detection (GC-MS) was used to analyze endosulfan in samples of poisoned fish pond water. The disperser, containing extraction solvent, was rapidly injected into the sample solution with a syringe, making a cloudy solution formed. Because of the extraction solvent rapid diffusing into the sample solution and getting in touch with the analyte in the cloudy solution, the analyte was quickly transferred into the extraction solvent so that the extraction equilibrium could be achieved in a short time. After centrifuging, the fine particles of extraction solvent were precipitated in the bottom of the conical test tube and then were determined by GC-MS. Results Under the optimum conditions the extraction rate of endosulfan in poisoned fish pond water was