水浴消解和微波消解-原子荧光法测定土壤中汞和砷的研究.pdfVIP

ofAnhui 安徽农业科学，Journal Agfi．Sci．2015，43(16)：90—92 责任编辑刘月娟责任校对李岩 水浴消解和微波消解一原子荧光法测定土壤中汞和砷的研究 刘欢欢，徐云龙，赵杰 (苏州国环环境监测有限公司，江苏苏州215000) 摘要[目的]为比较水浴消解和微波消解一原子荧光法两种方法对测试土壤中的汞和砷的影响。[方法]采用水浴消解和微波消解对 土壤样品(I。样品和2。样品)的精密度、准确度和回收率。[结果]水浴消解法和微波消解法的检出限、精密度、准确度和回收率均能满足 土壤的检测要求。[结论]微波消解法使用的仪器设备较先进，耗时短，溶剂用量少，溶样效果好。且有更好的精密度、准确度和回收率。 关键词水浴消解；微波消解；原子荧光法；汞；砷 中图分类号S158．4文献标识码A 文章编号0517—66ll(2015)16—090—03 Determinationof andArsenicin WaterBath andMicrowave Fluorescence Mercury S棚by Dlges60ll Di窖estion-AtomicSpectrometry U[U GuohuanEnvironmentDetection Hun-huan，XUYun-long，殂弧O．1ie(Suzhou Co．，hd，Suzhou，Jiangsu215000) Abstract researchaimedto theinfluenceofwater andmicrowave fluorescence f 0biective]The study I)alh spectrom． digestion digestion．atomic onthecontentof and Method1he were withwaterbath andmicrowave mero etry mercuryarsenic．f 1 samplespretreated digestion digestion．and of was andarsenicinseil weredeterminedatomicfluorescence differencethetwo methods cult samples bY spr(-tmphotometry．The pretreatment diseussedthe and oftwosoilstandard and twosoll by recovery substance(GSBZ50012-88GBW07453)andsamples(1-and precision。accuracy resultsofthesoilmett}le ofthe methodofmicrowave 2‘sample)．『Resultl‰detectionrequirementstandard．fConclusion]111epretreatment had anditsinstnmlent WaSmoreadvanced．Italso lesstimeandsolvent． better and digestion precision．accuracyrecovery equipment spent wordsWaterbath fluorescence spect