测试温度对La0.75Mg0.25Ni3.5Si0.10贮氢合金动力学性能影响研究.pdfVIP

（4）特种功能材料 测试温度对LaMgNiSi贮氢合金动 0.750.253.5 0.10 力学性能影响的研究 林玉芳，郭佩佩，郭世海，张羊换，赵栋梁 钢铁研究总院功能所，北京 100081 摘要：本论文以 LaMgNiSi退火合金为研究对象，采用交流阻抗谱和电位阶跃方法，对其不同使用 0.750.253.5 0.10 环境温度下（30~70℃）的高倍率放电特性和动力学性能进行了深入的研究。研究结果表明：合金的动力学 性能是由电化学反应与氢在合金体内的扩散共同控制的，合金表面的电荷传递电阻随温度升高而减小，高 温提高了电极表面电化学反应速度；但合金存在最佳氢扩散温度，当温度过高后，由于释氢等副反应的增 加，以及氧化腐蚀反应的加剧等原因，使合金的扩散系数反而减小；在合金电极表面电化学反应速度与氢 扩散系数共同作用下， LaMgNiSi合金高倍率放电性能在45℃时最佳。 0.750.253.5 0.10 关键词：贮氢合金，温度，电化学阻抗，氢扩散系数 Research on the effect of temperature on the electrochemical kinetic performance of La0.75Mg0.25Ni3.5Si0.10 metal hydride electrode alloy LIN Yufang, GUO Peipei, GUO Shihai, ZANG Yanghuan, ZHAO Dongliang (Department of Functional Material Research, Central Iron and Steel Research Institute, Beijing 100081) Abstract: In this paper, the high-rate discharge ability and dynamic characteristic of La0.75Mg0.25 Ni3.5 Si0.10 annealed alloy under 30~70 ℃ has been researched, by using electrochemical impedance spectrum (EIS) and constant potential-step discharge technique. The results show: the dynamic characteristic of the alloy is controlled by both the electrochemical reaction rate and the speed of hydrogen diffusion in bulk. The charge transfer resistance is decreased with testing temperature, and the electrode surface electrochemical reaction rate is improved under high testing temperature. But for La0.75Mg0.25 Ni3.5 Si0.10alloy, hydrogen diffusion coefficient will be decreased when the testing temperature is above the optimal temperature (45℃), due to the escape of the finite hydrogen in alloys being accelerated, and also the oxide film becomes thicker at high testing temperature. The increase of electrochemical reaction rates and the decrease of hydrogen diffusion speed together determine the hig