SDS-PVP水溶液中超细镍粉的制备.pdf

物理化学学报(Wuli Huaxue Xuebao) August A cta Phys. Chim. Sin., 2008, 24(8) ：1513-1518 1513 [Note] SDS PVP 水溶液中超细镍粉的制备 阮小云 方 云* 樊 晔 ( 南大学化学与材料工程学院, 苏无锡 214122) 摘要: 在十二烷基硫酸钠(SDS) 聚乙烯吡咯烷酮(PVP)混合水溶液中, 采用水合肼还原氯化镍制备超细镍粉. SEM 结果表明, 该超细镍粉为球形, 表面呈现针状叠合的特殊形貌. XRD 结果表明, 该超细镍粉由平均粒径约为 10 nm 的面心立方结构(fcc) 的原生纳米镍晶粒组成, 且主要沿(111)晶面生长. TEM 清晰观察到原生纳米镍晶粒 在PVP 的空间桥联作用下 组装成超细镍粉的中间过程. SDS PVP 的组成对超细镍粉的粒径和表面形貌有显 著影响, 在一定浓度范围内, 随着SDS 或PVP 浓度增大, 原生纳米镍晶粒和超细镍粉的平均粒径均呈减小趋势, 表明通过改变SDS PVP 组成可以调控超细镍粉的粒径和形貌. 关键词: 超细镍粉; 制备; 十二烷基硫酸钠; 聚乙烯吡咯烷酮 中图分类号: O648 Preparation of Ultrafine Nickel Powders in SDS PVP Aqueous Solution RUAN Xiao Yun FANG Yun* FAN Ye (School of Chemistry and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China) Abstract: Ultrafine nickel powders were prepared from nickel chloride reduced by hydrazine in aqueous solution of sodium dodecyl sulfate (SDS) polyvinylpyrrolidone (PVP). SEM results showed that the reduced products were sphere with special needle like morphology. XRD displayed that the spherical ultrafine nickel powders were self assembled into by the primary pure crystalline nanonickel of face centric structural (fcc) with the mean crystal size about 10 nm, and grown preferentially along ( 111) lattice plane . The process that the primary pure crystalline nanonickel self assembled into the ultrafine nickel powders in virtue of the coupling of PVP chain was clearly observed by T