乙烯基树脂合成的副反应.pdfVIP

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Polymer Bulletin 16, 153-157 (1986) Polymer Bulletin 9 Springer-Verlag 1986 Synthesis Synthesis of vinyl ester resins Evidence of secondary reactions by 13CNMR B.S. Rao, P.J. Madec, and E. Marechal* Laboratoire de Synthese Ma~cromol6culaire(UA 24- CNRS), Universit~ Pierre et Marie Curie, 12, rue Cuvier, F-75005 Paris, France SUMMARY The reaction of diglycidyl ether of bisphenol A with methacrylic acid was carried out in the presence of an amine catalyst (imidazole) or a chromium chelate (chromium diisopropylsalicylate). The resin products were analyzed by gel permeation chromatography and13C nuclear magnetic resonance spectroscopy. With both catalysts the reaction is characterized by an isomerization of the hydroxy-ester. The imidazole-catalyzed reaction product gave transesterification species in addition to isomerization product whereas these were absent with the chromium derivative catalyst. INTRODUCTION Vinyl ester resins form a family of thermosetting resins which combine the excellent thermal and mechanical properties of epoxy resins with the ease of processing and rapid curing of polyester resins. They are generally producted by addition of ethylenically unsaturated mono carboxylic acid to an epoxy backbone in the presence of basic catalys- ts(|,2). ~CH= Their resistance to acids, alkaline bases and chemicals is outstan- ding. Unfortunately the shelf life of the resin is very low when compared to that of epoxidesand unsaturated polyesters(3). Moreover, when using a basic catalyst like imidazole we often observed some styrene insoluble gel particlesin the resin. This could be due to the fact that under such basic cond

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