化学专业英语——无机化合物的命名.pptVIP

* * Vocabulary 1. coordination compound 配位化合物 2. complex 络合物 3. formula ( formulae 复数） 分子式， 公式 4. ligand 配体 5. cation 阳离子 （cathode 阴极） 6. anion 阴离子 （anode 阳极） 7. precede Vt. 1) 优于…..，位于…..之前； 比…..优先；（地位等）高于….. The motorcade was preceded by motorcycles. 摩托车为车队作先导 8. bracket n. 1) 托架 2) [复]括号 ( 指[ ], , ( ), { } ) 10. spell out 讲清楚， 清楚地说明 9. parentheses n. 圆括号 Nomenclature of Coordination Compound: IUPAC Rules Cation named before anion for ionic compound When naming complexes Ligands are named first alphabetically Metal atom / ion is named last Oxidation state given in Roman numerals follows in parentheses Names of anionic ligands end with suffix -o Chang –ide to -o Chang –ite to -ito Chang –ate to -ato Nomenclature : IUPAC Rules Neutral ligands referred to by their usual names Example: NH2CH2CH2NH2 ethylenediamine Exceptions: Water, H2O = aqua Ammonia, NH3 = ammine Carbon monoxide , CO = carbonyl Nitrogen oxide , NO = nitrosyl ethylenediamine H2NCH2CH2NH2 ? acetato CH3COO- pyridine C5H5N ? carbonato CO32- dinitrogen N2 ? oxalato C2O42- dioxygen O2 ? cyano CN- Carbonyl CO ? Hydroxo OH- Nitrosyl NO ? oxo O2- aqua H2O ? fluoro F- ammine NH3 ? bromo Br- Names Neutral Ligands ? Names Anionic Ligands Nomenclature : IUPAC Rules Greek prefixes are used to designate the number of each type of ligand in the complex ion, e.g. di-, tri- and tetra-. If the ligand already contains a Greek prefix (e.g. ethylenediamine) or if it is polydentate ligands (ie. can attach at more than one binding site) the prefixes bis-, tris-, tetrakis-, pentakis-, are used instead. Numerical prefixes dodeca 12 octa 8 tetra (tetrakis) 4 undeca 11 hepta 7 tri (tris) 3 deca 10 hexa (hexakis) 6 di (bis) 2 nona (ennea) 9 penta (pentakis) 5 mono 1 Prefix Number Prefix Number Prefix Number Nomenclature : IUPAC Rules If the complex is an an