高性能聚酰亚胺纳米复合纤维膜的电纺制备和导电性能的研究.pdfVIP

高性能聚酰亚胺纳米复合纤维膜的电纺制备与导电性能研究 孙芳查俊伟姚志强党智敏 北京科技大学高分子科学与工程系，新能源与环境高分子材料实验室，北京市海淀区学院 路30号 100083 碳纳米管由于其独特的力学、磁学、电学等性能，在电极材料、纳米电子器件、复合材 料等多方面得到广泛应用。尤其是随着电纺丝技术的兴起，聚合物/碳纳米管纳米复合纤维的 研究越来越受到极大关注，其已经成为现在纳米科学的热门。聚酰亚胺作为一种特种工程材 料具有各种优良特性广泛应用在航空、航天、电子、电气等领域，但是，关于聚酰亚胺/碳纳 米管纳米纤维膜制备及其综合力学性能、导电机理的研究仍然很少。本论文通过对电纺工艺 参数的调控制备可控结构纳米复合纤维膜，建立导电纤维的微观结构与电性能和力学性能的 关联，并对导电机理进行了深入研究[1-3]。 FabricationandConductivePropertiesofHighPerformance PolyimideNanofibercompositesbyElectrospinning ZHA Junwei SUNFang YAOZhiqiangDangZhimin LaboratoryofPolymerMaterialsforNewEnergyandEnvironment,DepartmentofPolymer ScienceandEngineering,UniversityofScienceandTechnologyBeijing,Beijing100083 Abstract:Carbonnanotubes(CNTs)havebeenwidelyusedinmanyfieldssuchaselectrodes, nanometerelectrondevice,andcompositesetc,duetoexcellentelectrical,mechanical,thermaland magneticproperties[1].Polyimide(PI)isparticularlyattractivefortheiroutstandingthermal, stabilityandgoodmechanicalpropertiesandusuallyusedashigh-performanceengineering plastics[2].Withthedevelopmentoftheelectrospinningtechnology,PInanocompositescontaining CNTshavereceivedmoresignificantattention.However,onlyafewstudieshavedescribedthe conductivemechanismandmechanicalpropertiesofPI/CNTsnanocompositesbyelectrospinning. Inthispaper,inordertoimprovetheinterfacialinteractionandcompatibilitybetweentheMWNTs andthematrix,pristineMWNTswerefirstlytreatedwithconcentratedHNO3toobtainthe acid-functionalizedMWNTs[3],andthentheelectrospinningsolutionsarepreparedviain-situ polymerization.Atlast,PInanofibersandthenanofibercompositeswithMWNTsconcentrations rangingfrom3to20vol％ werefabricatedbyelectrospinning.Thecontrollablestructuresuchas parallelfiberisformed.Therelationshipbetweenstructureandelectricalpropertiesofthe nanofibercompositesarestudied.Tosumup,suchahomogeneityapproachtofabricate high-perfor