锌电积新型阳极与电积新工艺研究进展.pdfVIP

· 86· 材料导报 锌电积新型阳极与电积新工艺研究进展+ 衷水平，赖延清，蒋良兴，田忠良，李 劫，刘业翔 (中南大学冶金科学与工程学院，长沙410083) 摘要 锌电积长期采用Pb-Ag合金为阳极。该阳极存在析氧过电位高、易腐蚀且污染阴极锌等问题，因此人 们研究了各类新型阳极与电积新工艺。综述了铅基多元合金阳极、复合电催化铅基阳极和钛基电催化阳极及Zn-NaCl04联 合电解和Hz扩散阳极电积的研究与应用现状，展望了锌电积新型阳极与电积新工艺的发展方向。 关键词 锌电积铅基合金阳极钛基电催化阳极联合电解气体电积 Research ofNewAnodeandTechnicsforZinc Development ZHONG Jie，LIU Shuiping，LAIYanqing，JIANGLiangxing，TIANZhongliang，LIYexiang (Schoolof Scienceand South 410083) Metallurgy Engineering，CentralUniversity，Changsha Abstract with isuesdas anodeinzinc encountered Pb-Agalloy permanent electrowinning．Theproblems lead are evolution and contaminationofcathodes．Thereforedif— oxygen alloyshigh overpotential，corrosionsubsequent this ferentkindsofnewanodesandtechnicsforzinc havebeenstudied．In constitution，re— electrowinning paper，the and statusofleadbasedanodesandtitaniumbased combinationand quo DSA，Zn-NaCl04electrolysis sear．ch application are the ofthe directionofzince— H2diffusion technicsreviewed．Atsametime，the electrowinning expectiondeveloping is lectrowinning given． wordszinc based based Key electrowinning，leadalloyanodes，titaniumelectrocatalytic electrolysis，gaselectrowinning 相对于火法炼锌工艺，湿法炼锌由于具有生产能力大、效率 1铅