非常规汽油脱硫技术.pdfVIP

Jan. 2004 现代化工 24 1 56 Mode n Chemical Indust y 2004 1 非常规汽油脱硫技术 居沈贵 曾勇平 姚虎卿 ( 南京工业大学化工学院, 江苏 南京210009) : , , , , , , , , , , : ; ; ; ; ; ; :TQ113. 2 : A : 0253- 4320(2004) 01- 0057- 04 Unconventional desulfurization technology J U Shen-gui, ZENG Yong-p ing , YA O H u-qing ( College of Chemical Enginee ing, Nanj ing Unive sity of T echnology, Nanjing 210009, China) Abstract: It will be obvious to educe the cost of dusulfu ization by the st eam desulfu ization in which wate st eam is used as substitute of hyd ogen. Bio-desulfu ization technology in which enzyme substitutes the t aditional catalyze is gene ally ecognized. While the catalytic distillation desulfu ization is a technology that combines catalysis and distillation, it has the g eat advantages ove the t aditional hyd odesulfu ization. Some sulfides can be emoved by conve sion/ ext action desulfu ization in which some mixtu e of pola compounds was used. In o de to enhance the desulfu ization efficiency, some oxidative additives a e demanded, but it will induce the equi ement of accesso ial assembly and has limited desulfu ization efficiency. Such plasm and photochemical desulfu ization, memb ane p ocess desulfu ization, ult asonic desulfu ization belong to physical methods, so they a e ve y significant to envi onment. Adso ptive desulfu ization is anothe p omising desulfu ization technology in which sulfides can be emoved completely f om the FCC f action and the loss of p oducts will be tiny and octane numbe can be igno ed. Key words: gasoline; desulfu ization; biocatalysis; catalytic distillation; ext action; adso ption;