两性聚丙烯酰胺絮凝剂的制备及其在制革废水处理中的应用.pdfVIP

Preparation of Amphoteric Polyacrylamide Flocculant and Its Application in the Treatment of Tannery Wastewater Junfeng Zhu,1,2 Guanghua Zhang,1,2 Junguo Li1 1College of Chemistry and Chemical Engineering, Shaanxi University of Science Technology, Xi’an Shaanxi, China 2Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology, Xi’an Shaanxi, China Received 14 July 2010; accepted 12 August 2010 DOI 10.1002/app.33175 Published online 19 October 2010 in Wiley Online Library (). ABSTRACT: Through two-phase aqueous polymeriza- done was 1.2% and the weight percent of initiator was tion, amphoteric polyacrylamide (AmPAM) emulsion, as 4.0% of monomer total weight and m (acrylamide): m an environmental friendly flocculant for the tannery (DMC): m (AA) was 9: 5: 3, AmPAM achieved overall wastewater, was firstly synthesized using ammonium performance, good solubility, high stability, and applica- sulfate aqueous solution as the dispersion, using acryl- tion in a wide range of pH value between 4 and 10. The amide, cationic monomer ethylene methyl propenoyl-tri- flocculating rate was more than 90.0%. AmPAM floccu- methylammonium chloride (DMC), and anionic lant with both anionic group and cationic group pro- monomer acrylic acid (AA). The structure and properties vided a clear antipolyelectrolyte effect and a wide pH of the synthesized AmPAM were characterized by means value range of the application, especially for tannery of FT-IR measurement, and the effects of various factors wastewater. It had not only charge neutralization and were studied, such as dispersing