石墨_酚醛树脂复合材料双极板.pdf

石墨/酚醛树脂复合材料双极板 1 陈 惠，刘洪波，夏笑虹，杨 丽，何月德 （湖南大学材料科学与工程学院，长沙，410082 ） 摘要：采用模压热固化二步法，以酚醛树脂为粘结剂、天然鳞片石墨为导电骨料、炭黑为添加剂制备质子交换膜 燃料电池用的复合材料双极板。系统地研究了不同种类石墨对石墨/酚醛树脂复合材料电性能和抗弯强度的影响。 结果表明，天然鳞片石墨为导电原料时，所制备的石墨/酚醛树脂双极板的性能最好。实验结果还表明：添加导电 炭黑能有效地提高石墨/酚醛树脂复合材料的电导率；在复合材料制备中加入 4wt% 的碳纤维，碳纤维-石墨/酚醛 树脂复合材料的抗弯强度提高了29%，碳纤维表面液相氧化处理能有效提高纤维与基体间的结合强度，随着处理 时间的延长与处理温度的升高，碳纤维-石墨/酚醛树脂复合材料的电导率和抗弯强度都有很大程度的提高；最终 固化温度主要影响酚醛树脂的交联程度，随着最终温度的升高，酚醛树脂的交联程度增加，电导率增大，但抗弯 强度有一定程度的减小。 关键词：燃料电池；双极板；复合材料；天然石墨；聚合物；电导率；抗弯强度 中图分类号：TB331,TB332 文献标志码：A Graphite/resin composite bipolar plate CHEN Hui, LIU Hongbo, XIA Xiaohong, YANG Li, HE Yuede (Materials science and engineering college of Hunan university,, Changsha 410082) Abstract: The composite bipolar plate for proton exchange membrane fuel cell, resin as a binder, natural graphite as the conductive aggregate, carbon black as additive ，used the molding and thermosetting two-step method. The effects of graphite species on the conductive properties and the flexural strength of the graphite/resin composites were investigated and analyzed systematically. The results show that there will be the best performance when the natural flake graphite was used as conductive raw material. The electrical conductivity of the graphite/resin composites can effectively be improved if conductive carbon black(CB) is added. In the preparation of graphite/resin composites, if adding 4wt% carbon fiber, the flexural strength of the carbon fiber-graphite/resin composites bipolar plates is improved by 29%. The liquid phase oxidation processing of carbon fiber surface can effectively improve the bonding strength between the fibers