二硫代磷酸盐提高活性在白炭黑配方中的应用.pdfVIP

Technical report No. 70 Application of dithiophosphates to improve dynamic properties in silica compounds Hans-Martin Issel, Martin Säwe, Rhein Chemie Rheinau GmbH, Mannheim, Germany [ Contact: hans-martin.issel@ · martin.saewe@] Key words: Silica compounds, Rhenocure® SDT/S, Rhenocure® ZBOP/S, Rhenofit® GE 1914, dithiophosphates, DPG replacement, dynamic properties, rolling resistance, wet skid, ice trac- tion, viscosity, shelf life, processing. Abstract Dithiophosphates show numerous im- provements when used in silica filled com- pounds, e.g. for tire treads (Technical Report No. 68). Some of the challenges when using these co-accelerators in silica compounds are fast cure and viscosity increase over shelf life. New synergistic combinations with a tailor-made new pro- cessing stabilizer Rhenofit® GE 1914* help to overcome difficult mixing. Rhenocure® SDT/S and Rhenocure® ZBOP/S can sub- stitute DPG in tire tread compounds. Very positive effects have been found with re- gard to heat stability, dynamic heat build- up as well as dynamic modulus and tan δ of the compound. A solution SBR/BR compound composed with a high load of silica, coupled with a disulfane type silane was mixed in three steps to achieve sufficient coupling. The formulation for testing is given in table 1. Mixing took place in a two-step internal mixing process and a final pass on the open mill. *) Rhenofit® GE 1914 is the silica-bound form of GE1872. The active ingredient is 75%. 2 e Tab. 1: Test formulation, 3-pass mixing g a Rhenogran® Rhenocure® Rhenocure® Rhenocure® P Component DPG-80 ZBOP/S SDT/S ZBOP/S + ® control Rhenofit