《Effect of Dodecylbenzene Sulfonic Acid Used as Additive on Residue Hydrotreating》.pdfVIP

China Petroleum Processing and Petrochemical Technology Process Research 2015, Vol. 17, No. 1, pp 82-88 March 31, 2015 Effect of Dodecylbenzene Sulfonic Acid Used as Additive on Residue Hydrotreating Sun Yudong; Yang Chaohe (College of Chemical Engineering, China University of Petroleum, Qingdao 266580) Abstract: The effect of additive—dodecylbenzene sulfonic acid (DBSA)—on residue hydrotreating was studied in the au- toclave. The results showed that the additive improved stabilization of the colloid system of residue, which could delay the aggregation and coke formation from asphaltenes on the catalyst, and make heavy components transformed into light oil. The residue conversion in the presence of this additive increased by 1.94%, and the yield of light oil increased by 1.53% when the reaction time was 90 min. The surface properties of the catalyst in the presence of this additive were better than that of the blank test within a very short time (30 min) and deteriorated rapidly after a longer reaction time due to higher conversion and coke deposition. Compared with the blank test, the case using the said additive had shown that the structure of hydrotreated asphaltene units was smaller and the condensation degrees were higher. The test results indicated that the additive could improve the hydrotreating reactivity of residue via permeation and depolymerization, the heavier components could be transformed into light oil more easily, and the light oil yield and residue conversion were higher for the case using the said additive in residue hydrotreating process. Key words: residue hydrotreating; dodecylbenzene sulfonic acid; product distribution; catalyst properties