《Effects of Electron Donor and Different Solvents on Polarizability and Second Hyperpolarizability of Diradical Complex Involving XXB Al Ga》.pdfVIP
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CHEM.RES.CHINESEUNIVERSlllES20l 12
2,28(2),308——3
EfkctsofElectronDonorandDifI.erentSolventson
andSecond of
PolarizabilityHyperpolarizability
Diradical
ComplexInVolVingX(X=B,Al,Ga)
LIU Guo.chun,LIU andSUN
Hai-bo,QIUYong.qing‘,YANG Chun.guaIlgShi-ling
Mnteriat
|nstinne西Ftlncnonnlchemist嘞Fnctllt)I巧Chemis臼x
NortllenstNormni i30024,P.R.Chi眦
Un如ersity,Chnngc}mn
Abstract111e sec∞d for diradical
singlet
polarizability(n)andhyperpolarizability(y)weresystemicallyinvestigated
resuItsshowttIatbothmea鲫dcanbe tuned
complexinvolvingX(X=B,Al,Ga)atom.The y ef瓷ctiVelybyVarying
the
thedis协nce A卸dawater atomX.Thelone ofelectmns厅om
R(betweencom口ound molecule)andacceptor pair
atomofthewater into vac柚torbital increasedthe characterand
O molecuIeenteredthe p ofatomX,which dimdical
the
ledtotheincreaseoftheaaIld continuum usedtotest
yvaIues.Furthermore,thepol撕zabIe model(PCM)was
e疗.cctS and solventsonthe口andvalues.Botlltheandvaluesofthestudieddimdical
a la(1b,
ofH20CCl4
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