《Hexagonal hematite platelets synthesized from pyrite cinders by hydrothermal process》.pdfVIP
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10.1007/s11771-011-0849-5
Hexagonalhematiteplateletssynthesizedfrompyritecindersby
hydrothermalprocess
LIUZhao-cheng ZHENGYa-jie
SchoolofMetallurgicalScienceandEngineering,CentralSouthUniversity,Changsha410083,China
Abstract:Well-crystallizedhexagonalhematite(a-Fe2O3)plateletsweresynthesizedbyhydrotherrnalprocess,usingahighly
concentratedferrichydroxideasprecursor.Theprecursorwaspreparedbyaddingammoniatotheferricsulfatesolutionwhichwas
obtainedbyleachingpyritecinderswithsulfuricacid.Structureandmorphologyofthesynthesizedproductswereinvestigatedby
X-raydiffraction,scanningelectronmicroscope,transmissionelectronmicroscopeandselectedareaelectrondiffraction.Theresults
revealthatthereactiontemperaturehassignificanteffectsonthestructure,sizeandshapeofthesynthesizedhematiteparticles.
Typicalhexagonalhematiteplatelets,about0.4-0.6μmindiameterand0.1μminthickness,werepreparedat230℃ for0.5h.Al3+,
containedinthesulfuricacidleachingsolutionasanimpurity,playsanextremelyimportantroleintheformationofhexagonal
hematite.Inaddition,apossiblemechanismabouttheformationofhexagonalhematiteplateletswasproposed.
hematite;α-Fe2O3;pyritecinders;hydrothermalprocess;hexagonalplatelets
Project(2008A090300016)supportedbytheKeyScienceandTechnologyItemofGuangdongProvince,China;Project(ZKJ2010022)
supportedbythePreciousApparatusOpeningCenterFoundationofCentralSouthUniversity,China
2010-09-07 2010-12-23
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