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植物油脂水解工艺及不饱和脂肪酸组成研究
DOI :CNKI:11-1759/TS1726.002 网络出版时间:2011-01-14 17:26
网络出版地址:/kcms/detail/11.1759.TS1726.002.html
∗
210042
g/g2:1
-v/v2:1,1.5h70
98.25%203.67mgKOH/g 109.89 g/100g
98%199mgKOH/gGC-MS
94.88%84.07%
81.90%77.84%77.19%
85.36%58.01%56.81%55.31%
42.16%
7,10-
9-13.83%8,11-
24.37%9,12,15-6,9,15-60.01%
TQ07,TQ031.5
Studies on hydrolysis processing of different vegetable oil
and compositions of iunsaturated fatty acid
LV Wei, JIANG Jian-chun, XU Jun-ming
(Institute of Chemical Industry of Forest Products,CAF;Key and Open Lab.on Forest Chemical
Engineering,SFA,Key Lab.of Biomass Energy and Materizal,Jiangsu Provienc,Nanjing210042,China)
Abstract:The preferable condition of basic hydrolysis for Jatropha curcas L.seed oil was
oil-water of mass ratio 2:1, ethanol-water of volume fraction 2:1, 1.5h for Saponification at
70 .The average of yeild,acid value and iodine value of fatty acid were 98.25%,203.67mgKOH/g
and 109.89 g/100g. The applicability of the process conditions of hydrolysis was investigated
through applicable experiments using cornus wilsoniana seed oil,tung oil,palm oil and soybean oil .
The experimental results indicated that the yield and acid value of fatty acid in different vegetable
fat were about 98% and 199mgKOH/g. After esterification the fatty acid was analyzed by
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