苯胺衍生物纤维的制备.pdfVIP

View Online / Journal Homepage / Table of Contents for this issue COMMUNICATION /chemcomm | ChemComm A general synthetic route to nanofibers of polyaniline derivatives Henry D. Tran and Richard B. Kaner* Received (in Berkeley, CA, USA) 3rd May 2006, Accepted 3rd July 2006 First published as an Advance Article on the web 7th August 2006 DOI: 10.1039/b605928g Nanofibrous mats of a wide variety of polyaniline derivatives acid. This solution is rapidly mixed with a solution of oxidant, can be synthesized without the need for templates or functional ammonium peroxydisulfate (50 mg), in 1 M acid. Upon addition dopants by simply introducing an initiator into the reaction of the oxidant, the characteristic color changes associated with the G formation of the polyaniline derivatives are observed within several 8 mixture of a rapidly mixed reaction between monomer and 2 9 seconds, an observation consistent with previous studies using 5 oxidant. 2 0 17 1 6 oligomers to synthesize chiral polyaniline nanofibers. The 0 B / 2 9 r 3 Since their discovery, conducting poly