AlCl3Al-MCM-41催化剂上萘与丙烯的烷基化反应.pdf

2010 Chinese Journal of Catalysis Vol. 31 No. 7 文章编号: 0253-9837(2010)07-0725-04 国际版DOI : 10.1016/S1872-2067(09)60080-2 研究快讯: 725~728 AlCl /Al-MCM-41 催化剂上萘与丙烯的烷基化反应 3 唐 华, 纪 敏, 王新葵, 贺 民, 蔡天锡 大连理工大学化学系, 辽宁大连 116012 摘要：采用两步气相法制备了 AlCl3/Al-MCM-41 催化剂, 在浆态鼓泡床反应器中考察了其催化萘和丙烯烷基化反应性能, 并通 过粉末 X 射线衍射、N2 吸附-脱附、吸附吡啶红外光谱及化学分析等方法, 表征了载体的物化性质及催化剂表面酸性. 结果表明, 在萘与丙烯的烷基化反应中, 具有与 2,6-二异丙基萘 (2,6-DIPN) 分子动力学尺寸相匹配的孔道和适当的[–O–AlCl2]担载量是提 o 高 AlCl /Al-MCM-41 催化剂活性和选择性的关键, 其中以较大孔径的 AlCl /H/Al-MCM-41 催化剂活性最高, 在 0.1 MPa, 85 C 反 3 3 应 5 h 时, 萘转化率达 82.1%, 2,6-DIPN 在 DIPN 中的摩尔含量达 32.2%. 关键词：萘; 烷基化; 丙烯; 固载化; 三氯化铝; MCM-41; 浆态鼓泡床反应器 中图分类号：O643 文献标识码：A Alkylation of Naphthalene with Propylene Catalyzed by Aluminum Chloride Immobilized on Al-MCM-41 * TANG Hua, JI Min , WANG Xinkui, HE Min, CAI Tianxi Department of Chemistry, Dalian University of Technology, Dalian 116012, Liaoning, China Abstract: AlCl3 catalysts immobilized on mesoporous Al-MCM-41 were prepared by a two step vapor method and their catalytic perform- ance was evaluated for the alkylation of naphthalene with propylene in a slurry bubble column reactor. The physico-chemical properties of the supports and catalysts were characterized by X-ray diffraction, N adsorption, and pyridine adsorption infrared spectroscopy. The halide