MnO2-CeO2Ti0.25Zr0.25Al0.5O1.75整体式催化剂的低温NH3选择性催化还原NO性能研究.pdf

第25卷第3期 无 机 化 学 学 报 V01．25No．3 2009年3月 CHINESEJOURNALOFINORGANICCHEMISTRY 485～490 低温NH3选择性催化还原NO性能研究 张秋林林 涛 李 伟 徐海迪 龚茂初 陈耀强★ (四川大学绿色化学与技术教育部重点实验室，成都 610064) 175～325℃之问NO转化率接近100％，而且TZAC表现出了较强的抗H，0和SO，性能。 关键词：低温选择性催化还原(SCR)；氮氧化物；催化；整体式催化剂 中图分类号：0614．332；0643．322文献标识码：A 文章编号：1001-4861(2009)03-0485-06 Performanceof Monolith forLow Mn02一CeOJTi峪Zrm2A10。0L75 Catalytic Catalyst Selective ReductionofNowith TemperatureCatalytic NH3 ZHANG LIN LI Qiu-LinTao WeiXUHai—DiGONGMao—ChuCHEN Yao—Qiang。 (The 610064) KeyLaboratoryofGreenChemistryTechnologyofMinistryofEducation,SichuanUniversity,Chengdu Abstract：Ti02(D，Ti0．5zro．502(TZ)andTi0．zcZr02sAlo．501．7s(TZA)werepreparedby monolith CO-precipitation．Three were and asactive Mn02Ce02 onT，TZand catalystspreparedusing componentssupported werecharacterized atlow catalysts byN2adsorption—desorption temperature，oxygenstorage andXPS．Thelow activitiesaswellasresistanceto and inthe ofexcessive temperaturecatalytic S02 H20 presence 02werestudied．Theresultsindicatethatthe of the catalyst largest surface mostsurfaceacidicamountandthe surface specific area，oxygen volume，the storagecapacity，pore