光谱分析解答.pdf

Answers to Problems Introduction to Spectroscopy, 4th edition Pavia, Lampman, Kriz, Vyvyan CHAPTER 1 ________________________________________________________________________ 1. (a) 90.50% carbon; 9.50% hydrogen (b) C H 4 5 2. 32.0% carbon; 5.4% hydrogen; 62.8% chlorine; C H Cl 3 6 2 3. C H NO 2 5 2 4. 180.2 = molecular mass. Molecular formula is C H O . 9 8 4 5. Equivalent weight = 52.3 6. (a) 6 (b) 1 (c) 3 (d) 6 (e) 12 7. The index of hydrogen deficiency = 1. There cannot be a triple bond, since the presence of a triple bond would require an index of hydrogen deficiency of at least 2. 8. (a) 59.96% carbon; 5.75% hydrogen; 34.29% oxygen (b) C H O 7 8 3 (c) C21H24O9 (d) A maximum of two aromatic (benzenoid) rings 9. (a) C H O (b) C H N (c) C H N O (d) C H O 8 8 2 8 12 2 7 8 2 5 12 4 10. Molecular formula = C H N O ; index of hydrogen deficiency = 6 8 10 4 2 11. Molecular formula = C H O ; index of hydrogen deficiency = 7 21 30 2 12. For the hydrolysis product: molecular formula = C H O ; index of hydrogen 6 12 6 deficiency = 1 For the original carbohydrate: m