基于电位突跃的润滑油酸值测定方法.pdfVIP

2009 11 Nov2009 34 11 LUBR ICAT ION ENG INEER ING V ol34 No11 DOI: 103969 / jissn0254 - 0150200911029 1 2 2 1. 246002; 2. 246001) : GB /T 7304, , , , , , : ; ; ; : TE6263 : B : 0254 - 0150 2009) 11- 106- 3 Determ ination ofAcid Number for Various Lubricating Oils Based on Potential Jump 1 2 2 Lu Kep ing L iu Hao Hu S ijiu 1Ch ina Pe tro leum and Chem ica l Corporation Anqing Branch Inspection Center, A nqing A nhu i 246002, Ch ina; 2 South W est A nhui Center of Product Qua lity Superv ision and Inspec tion, A nqing A nhu i 24600 1, Ch ina) Abstract: Th ere is almost no potent ial jum p w hen determ inating th e acid number of used lub ricating oilw ith the stand ards methods of GB /T 7304 for p etroleum produ cts, it need s to u se the tox ic nonaqueous standard buffer solut ion for end po int. A novel method b ased on potential jum p w as p resented. By u sing qu aternary ammon ium salt hydroxide w ith h igher b as icity as titrant, add ing the content of alcohol in m ixtu re solvent, enhan cing th e apparent acid ity of ac id ic com ponent by rep lacing w ater w ith alka line reagents, the m ethod can determ in e th e end point of titration b ased on potent ia l jum p, it is su itab le to determ ine the acid number of variou s of comp lex lubricant p rodu cts. Keywords: acid