《MicrowaveAssisted Decarboxylation of Sodium Oleate and Renewable Hydrocarbon Fuel Production》.pdfVIP

China Petroleum Processing and Petrochemical Technology Scientitic Research 2013, Vol. 15, No. 3, pp 19-27 September 30, 2013 Microwave-Assisted Decarboxylation of Sodium Oleate and Renewable Hydrocarbon Fuel Production Wang Yunpu1,2; Liu Yuhuan1,2; Ruan Rongsheng1,2; 2 1,2 1,2 Wen Pingwei ; Wan Yiqin ; Zhang Jinsheng (1. Nanchang University, State Key Laboratory of Food Science and Technology, Nanchang 330047; 2. Nanchang University, Engineering Research Center for Biomass Conversion, Ministry of Education, Nanchang 330047) Abstract: The carboxyl terminal of sodium oleate has a stronger polarity than that of oleic acid; this terminal is more likely to be dipole polarized and ionically conductive in a microwave field. Sodium oleate was used as the model compound to study the decarboxylation of oleic acid leading to hydrocarbon formation via microwave-assisted pyrolysis technology. The pyrolysis gas, liquid, and solid products were precisely analyzed to deduce the mechanism for decarboxylation of sodium oleate. Microwave energy was able to selectively heat the carboxyl terminal of sodium oleate. During decarboxylation, the double bond in the long hydrocarbon chain formed a p-π conjugated system with the carbanion intermediate. The resulting p-π conjugated system was more stable and beneficial to the pyrolysis reaction (decarboxylation, terminal allylation, isomeriza- tion, and aromatization). The physical properties of pyrolysis liquid were generally similar to those of diesel fuel, thereby demonstrating the possible use of microwave