漂珠钡铁氧体复合材料的制备及性能.pdf

漂珠／钡铁氧体复合材料的制备及性能 庞建峰 (淮阴工学院建筑工程系，江苏淮安223001) 摘要：采用溶胶．凝胶自蔓延燃烧法在漂珠表面包覆钡铁氧体颗粒涂层，制备了漂珠／钡铁氧体复合材料。 的显微形貌、结构、磁性能及吸波性能。结果表明，包覆后漂珠表面形成了均匀致密的钡铁氧体涂层，经850℃ 高温热处理2h后产生了钡铁氧体的晶相物质。制备的复合材料在2～18GHz范围内具有较好的介电损耗和磁损 耗性能，当吸波材料厚度为3．0mm时，在8．4GHz的反射损耗峰值为一15．44dB，反射损耗小于一12dB的带宽 为4．2GHz。 关键词：钡铁氧体；粉煤灰漂珠；溶胶．凝胶自蔓延燃烧；磁性能；吸波性能 中图分类号：TM277；TB33文献标识码：A 文章编号：1001．3830(2012)04．0039．05 and of ferrite Preparationpropertiescenospheres-bariumcomposites PANG Jian—feng andCivil Institute 223001，China FacultyofArchitectureEngineering,HuaiyinofTechnology,Huaian Abstract：Theof ash coatedwithbariumferrite were compositesfly cenospheres particlesuccessfullyprepared auto—combustionmethod．The bysol-gel morphology,crystalstructure，magneticproperties，electromagneticproperties andmicrowave behaviorofthe werecharacterized electron absorbing samples byscanning vectornetwork resultsshowedthat diffraction(XRD)，vibratingsamplemagnetometer(VSM)andanalyzer．The continuousanduniform ofbariumferriteisformedonthesurfaceof ash is addition，it coatinglayer fly cenospheres．In foundthatthe ofbariumferrite aftertheas—burnt wascalcinedat850。C crystalphases appears powdersofprecursorgel for2 exhibitbetter lossand loss withinthe h．Furthermore，thesamples dielectricmagneticproperties frequencyrange from2GHzto18GHz．Themaximumreflectionlossofthe materialreaches-15．44dBat8．4GHzwitha