2016Chemical_Shifts_SI.pdfVIP

Supporting Information NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist ,1 2 2 Gregory R. Fulmer,* Alexander J. M. Miller, Nathaniel H. Sherden, Hugo E. 3 3 2 2 Gottlieb, Abraham Nudelman, Brian M. Stoltz, John E. Bercaw, and Karen I. Goldberg1 1 Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700; 2 Arnold and Mabel Beckman Laboratories of Chemical Synthesis, and Caltech Center for Catalysis and Chemical Synthesis, Division of Chemistry and Chemical Engineering California Institute of Technology, Pasadena, California 91125; 3 Department of Chemistry, Bar Ilan University, Ramat Gan 52900, Israel. Corrections and Comments........................................................................................................ S2 1H NMR Data Table S1 ............................................................................................................ S3 13C NMR Data Table S2 ........................................................................................................... S5 Individual Solvent Tables – NMR Data Sorted by Chemical Shift Tables S3–S26 ............ S7 References .................................................................................................................................. S19 S1 Corrections and Comments In the preparation of this manuscript, several errors were discovered in the original paper1 and are reported herein. While comparing the 1H NMR spectral data obtained in toluene-d to that in C D , it was discovered that the 1H NMR chemical shifts 8 6 6 for acetic acid CH , acetonitrile CH and tert-butyl alcohol OH in C D had each 3 3 6 6 been misreported at 1.55 ppm in the original paper; the values have now been correctly listed as 1.52, 0.58, and 0.63 ppm, respectively.