BST KOH 做矿化剂Composition and shape control of single crystalline pdf.pdfVIP

ARTICLE IN PRESS Journal of Crystal Growth 310 2008 4132– 4137 Contents lists available at ScienceDirect Journal of Crystal Growth journal home Composition and shape control of single-crystalline Ba Sr TiO x ? 0–1 1x x 3 nanocrystals via a solvothermal route Xiao Wei, Gang Xu, Zhaohui Ren, Yonggang Wang, Ge Shen, Gaorong Han Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, PR China a r t i c l e i n f o a b s t r a c t Article history: Single-crystalline and well-dispersed barium strontium titanate Ba Sr TiO , x ? 0–1, BST nanocrys- 1x x 3 Received 16 January 2008 tals have been successfully synthesized in a shape- and composition-controlled manner using a facile Received in revised form solvothermal route. The microstructure and composition of the as-synthesized samples were 10 April 2008 investigated by X-ray diffraction XRD , transmission electron microscopy TEM , high-resolution TEM Accepted 21 April 2008 HRTEM , and energy-dispersive X-ray spectroscopy EDX . All the samples were identi?ed as cubic Communicated by M. Kawasaki Available online 7 May 2008 perkovsite phase by XRD. The average particle sizes, morphologies and compositions of all the as- synthesized samples signi?cantly depend on the Ba/Sr molar ratio in the initial reactants. The particle PACS: size gradually increases and the morphology ranges from irregular sphere to cube as the strontium 61.46.+w proportion increases in the BST. It has also been found that, in all cases, strontium is more readily 68.37.Lp 77.84.Dy incorporated into the BST nanocrystals compared with barium. Further experiments display that highly 81.07.Bc dispersed BaTiO3 and SrTiO3 nanocrystals could also be obtained with an acceptable crystallinity at 81.10.Dn room temperature by this solvothermal method. 2008 Elsevier B.V. All rights reserved. Keywords: