- 1、本文档共8页,可阅读全部内容。
- 2、原创力文档(book118)网站文档一经付费(服务费),不意味着购买了该文档的版权,仅供个人/单位学习、研究之用,不得用于商业用途,未经授权,严禁复制、发行、汇编、翻译或者网络传播等,侵权必究。
- 3、本站所有内容均由合作方或网友上传,本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺!文档内容仅供研究参考,付费前请自行鉴别。如您付费,意味着您自己接受本站规则且自行承担风险,本站不退款、不进行额外附加服务;查看《如何避免下载的几个坑》。如果您已付费下载过本站文档,您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等,请点击“版权申诉”(推荐),也可以打举报电话:400-050-0827(电话支持时间:9:00-18:30)。
查看更多
synthetic communication.pdf
SYNTHETIC COMMUNICATIONSw
Vol. 34, No. 6, pp. 1097–1103, 2004
Facile and Selective Synthesis of
Chloromethylpyridines and
Chloropyridines Using
Diphosgene/Triphosgene#
P. Narendar, B. Gangadasu, Ch. Ramesh, B. China Raju,
and V. Jayathirtha Rao*
Organic Chemistry Division II, Indian Institute of Chemical Technology,
Hyderabad, India
ABSTRACT
Diphosgene and triphosgene in the presence of amines were found to be
an excellent chlorinating agents with high selectivity for the preparation
of chloromethylpyridines and chloropyridines from picoline-N-oxides
and pyridine-N-oxides respectively.
Key Words: Chloromethyl pyridine; Chloropyridine; Diphosgene;
Triphosgene.
#IICT Communication No: 030808.
*Correspondence: V. Jayathirtha Rao, Organic Chemistry Division II, Indian Institute
of Chemical Technology, Hyderabad-500007, India; E-mail: jrao@iict.res.in.
1097
DOI: 10.1081/SCC-120028642 0039-7911 (Print); 1532-2432 (Online)
Copyright # 2004 by Marcel Dekker, Inc.
ORDER REPRINTS
1098 Narendar et al.
Chloromethylpyridines and chloropyridines constitute an important class
of compounds in the preparation of pharmaceuticals, dyes,[1] and pesticides.[2]
The most common method for the preparation of chloromethylpyridines and
chloropyridines involve the chlorination of picolines[3] and pyridine-N-
oxides[4] with reagents such as POCl ,[5] SO Cl ,[6] phosgene in DMF,[7]
3 2 2
您可能关注的文档
- RICS_Valuation_Standards__6th_edition_-_Chinese中文.pdf
- Risk-Based Prioritization among Air Pollution Control Strategies.pdf
- Risk_of_coffee.pdf
- RLB_Hong_Kong_and_China_Report_September_2016.pdf
- Robust Channel Estimation and Detection for Uplink Control Channel in 3GPP-LTE.pdf
- Robust control of delay systems a sliding mode control design via LMI.pdf
- Robust control of nonlinear uncertain systems via sliding mode with backstepping design.pdf
- Robust model predictive control for nonlinear discrete time systems.pdf
- Robust Sampled-Data Control of Linear Singularly Perturbed Systems.pdf
- Rock damage control in bedrock blasting excavation for a nuclear power plant.pdf
- System Coupling帮助中的实例.pdf
- Tackling Problems in Chinese-English Translation.pdf
- Tamm states of one-dimensional metal-dielectric photonic crystal.pdf
- Tax Structure for China Operation.ppt
- TB_US_TaxRefunds_2016_Chinese_pack.pdf
- TCVB-Traditional Chinese Villages Bulletin-02a.pdf
- TD1583-3A_DC-DC_降压稳压IC.pdf
- Teaching intercultural communication in university level.pdf
- Tebis培训_CAM.pdf
- Teen Court A Way to Combat Teenage Crime and Chemical Abuse.pdf
文档评论(0)