溶解度参数法计算超临界流体的溶解度.pdfVIP

36 2 V o l. 36 N o. 2 2008 2 CHEM ICA L ENG IN EER ING ( CH INA ) Feb. 2008 王伟彬, 银建中, 张礼鸣 ( , 116012) : 2 , , , , , 3, 11 CO 2 10% , , , : ; ; ; : O 642. 4; O 64 5. 12 : A : ( 2008) Solubility parametermethod for supercritical fluids solubility calculations WANG W eibin, YIN Jianzhong, ZHANG iming ( School of Chem cal Eng neer ng, Dal an Un vers ty o f T echnology, Dal an 116012, L aon ng P rov nce, Ch na) Abstract:T herm odynam c mode l and em p r cal form ula are often used n the calcu la t on o f so lute so lub l ty n supercr t ca l flu ds. Em p r ca l form u la s w dely used due to ts sm ple form and low error, and even super or to therm odynam c m ode.l Dens tydependent em p r cal formu la s deve loped nto m any form s. T he so lub l ty param eterdependent em p r cal formu la w as establ shed w th three tem perature ndependent param eters. T he solub l t es of 11 k nds o f sol d n supercr t ca l CO , ethane and ethy lene w ere ca lculated w th th s m ethod. T he 2 average relat ve dev at on s about 10% from exper m enta l data. Com pared w th dens ty, the d fference betw een solub l ty param eter of so lvent and so lu te can reflect the so lub l ty d rect ly, thu s m ore attent on should be pa d to solub l ty param eter. Key words: supercr t cal f lu d; so lub l ty; solub l ty param eter; em p r ca l form ula , 1 [ 2 ] :