《A convenient method for the conversion of [Sn3S4]》.pdf

Polyhedron 26 (2007) 1098–1104 /locate/poly A convenient method for the conversion of [Sn S ]2 to 3 4 [Sn S (l -OH)]: Syntheses, structures and characterizations 3 3 3 of (Bu N)[Sn (l -OH)S (edt) ] Æ DMF and 4 3 3 3 3 (Bu N)[Sn (l -OH)S (edt) ] Æ H O (edt = 1,2-ethanedithiolate) 4 3 3 3 3 2 Long-Sheng Wang, Tian-Lu Sheng, Jian-Jun Zhang, Sheng-Min Hu, Rui-Biao Fu, Xin-Tao Wu *, Ya-Min Li, Xi-He Huang, Sheng-Chang Xiang State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China Received 27 June 2006; accepted 28 September 2006 Available online 10 October 2006 Abstract Two new trinuclear tin(IV) oxy-sulfide complexes, (Bu N)[Sn (l -OH)S (edt) ] Æ DMF (1) and (Bu N)[Sn (l -OH)S (edt) ] Æ H O (2), 4 3 3 3 3 4 3 3 3 3 2 which are the same salt with different solvates, were unexpectedly obtained by the reaction of (Bu N) [Sn S (edt) ] with CuCl (or 4 2 3 4 3