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《] Nanocrystalline silicon and carbon nanotube nanocomposites .》.pdf
Pure Appl. Chem., Vol. 80, No. 11, pp. 2513–2520, 2008.
doi:10.1351/pac200880112513
© 2008 IUPAC
Nanocrystalline silicon and carbon nanotube
nanocomposites prepared by pulsed laser
fragmentation*
ˇ ˇ ‡
Vladimir Svrcek
Research Center for Photovoltaics, National Institute of Advanced Industrial
Science and Technology (AIST) Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki,
305-8568, Japan, and Nanoarchitectonics Research Center, AIST, Central 5,
1-1-1 Higashi, Tsukuba, Ibaraki 305 8565, Japan
Abstract : This paper outlines the synthesis of nanocrystalline silicon (nc-Si) by nanosecond
pulsed laser fragmentation of Si micrograins in liquid solutions, and characterization of the
products. We compare micrograin fragmentations in deionized water, and in undoped and
phosphorus-doped ethylpolysilicate (C H O[SiO(C H O) ] C H ) based polymers. We
2 5 2 5 2 n 2 5
show that dissolution and subsequent laser fragmentation of micrograins is more efficient in
both polymeric media than in water. In the case of water, micrograin surface wetting by
ethanol prior to introduction into water is essential to achieve fragmentation. Prepared
nc-Si/polymer nanocomposites display visible photoluminescence (PL) (~430 nm) at room
temperature. The phosphorus polymer induces a blue shift of the PL peak. In addition, in-
duced shock waves generated at sufficiently high laser irradiation intensities (4.3 mJ/pulse)
cause carbon nanotube (CNT) cavities to be filled by freshly prepared luminescent
nc-Si/polymer nanocomposite.
Keywords: silicon nanocrystals; photolumines
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