《] Nanocrystalline silicon and carbon nanotube nanocomposites .》.pdf

Pure Appl. Chem., Vol. 80, No. 11, pp. 2513–2520, 2008. doi:10.1351/pac200880112513 © 2008 IUPAC Nanocrystalline silicon and carbon nanotube nanocomposites prepared by pulsed laser fragmentation* ˇ ˇ ‡ Vladimir Svrcek Research Center for Photovoltaics, National Institute of Advanced Industrial Science and Technology (AIST) Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki, 305-8568, Japan, and Nanoarchitectonics Research Center, AIST, Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305 8565, Japan Abstract : This paper outlines the synthesis of nanocrystalline silicon (nc-Si) by nanosecond pulsed laser fragmentation of Si micrograins in liquid solutions, and characterization of the products. We compare micrograin fragmentations in deionized water, and in undoped and phosphorus-doped ethylpolysilicate (C H O[SiO(C H O) ] C H ) based polymers. We 2 5 2 5 2 n 2 5 show that dissolution and subsequent laser fragmentation of micrograins is more efficient in both polymeric media than in water. In the case of water, micrograin surface wetting by ethanol prior to introduction into water is essential to achieve fragmentation. Prepared nc-Si/polymer nanocomposites display visible photoluminescence (PL) (~430 nm) at room temperature. The phosphorus polymer induces a blue shift of the PL peak. In addition, in- duced shock waves generated at sufficiently high laser irradiation intensities (4.3 mJ/pulse) cause carbon nanotube (CNT) cavities to be filled by freshly prepared luminescent nc-Si/polymer nanocomposite. Keywords: silicon nanocrystals; photolumines