两种离子源技术气相色谱质谱法检测茶叶中酰胺类除草剂的残留量.pdfVIP

2007 9 Vol. 25 No. 5 September 2007 Ch inese J ourna l of Chrom atog rap hy 753~ 757 沈伟健, 徐锦忠, 杨雯筌, 沈崇钰, 赵增运, 丁 涛, 吴 斌 (, 2 10001) : (EI)(NCI)(GC S) 12 , , , EI NCI , , 10, 20 40 g/kg 3 50% ~ 110%, (RSD) 109%, EI, NCI( ),,NCI EI;, 20 g/kg, , NCI EI 1 : ;;; ; : O658 : A : 100087 13(2007 : Determ ination ofAcetanilideHerbicideResidues in Tea by Gas ChromatographyMass Spectrometry with Two Different Ionization Techni ues SHEN Weijian, XU Jinzhong, YANGWenquan, SHEN Chongyu, ZHAO Zengyun, DING Tao, WU Bin (Labor atory of Food, J ian gsu En try E it In spect ion and Qu ar an tin e Bu r eau, N an jin g 210001, China ) Abstract: An analyticalmethod of solidphase extractiongas chromatographymass spectrome trywith two different ionization techniques was established for smi ultaneous determination of 12 acetanilide herbicide residues in tealeaves. Herbicideswereextracted from tealeaf samples with ethylacetate. The extractwas cleanedup on an active carbon SPE column connected to a FlorisilSPE column. Analytical screeningwas determinedby the techniqueofgas chromatogra phy (GC)mass spectrometry ( S) in the selected ion monitoring (SI ) mode with either electron mi pact ionization (EI) or negative chemical ionization (NCI). It is reliable and stable that the recoveriesofallherbicideswere in the range from 50% to 110% atthreespiked levels, 10 g/kg, 20 g/kg and 40 g/kg, and the relative standard deviations (RSDs) werenomore than 109%. The two different ionization techniquesare complementary asmore ion fragmenta tion information can be obtained from the EImodewhilemoremolecular