二元混合离子液体的电导率与离子间的缔合作用.pdfVIP

物理化学学报(Wuli Huaxue X uebao) October A cta Phys. -Chim. Sin. 2013, 29 (10), 2 107-2 113 2 107 [Article] doi: 10.3866/PKU.WHXB201304 172 元混合离子液体的电导率与离子间的缔合作用 宁 汇 侯民强 杨德重 康欣晨 韩布兴* ( 中国科学院化学研究所, 中国科学院胶体界面与化学热力学重点实验室, 北京分子科学国家实验室, 北京100190) 摘要: 在293.15-323.15 K 范围内, 测定了 13 种常见离子液体及其25 组混合体系的电导率. 利用 Vogel-Tammann-Fulcher (VTF)方程对电导率数据进行拟合, 并通过方程式中的拟合参数分析了离子液体混合 后其阴阳离子间缔合作用的变化规律. 结果表明, 在相同温度下, 离子液体的阳离子侧链越短, 阴离子电荷越分 散, 阴阳离子间的氢键作用力越弱, 离子液体的电导率越大, 其中阴离子的影响比阳离子更明显. 混合离子液体 中离子间的缔合作用不仅与阴阳离子的种类有关, 而且与混合物的组成有关. 关键词: 离子液体; 二元混合; 电导率; 离子缔合; VTF 方程 中图分类号: O642 Ionic Association in Binary Ionic Liquids by Conductivity NING Hui HOU Min-Qiang YANG De-Zhong KANG Xin-Chen HAN Bu-Xing* (Institute of Chemistry, Chinese Academy of Sciences, CAS Key Laboratory of Colloid, Interf ace and Chemical Thermody namics, Beijing National Laboratory f or Molecular Sciences, Beij ing 100190, P. R. China) Abstract: In this study, the conductivity of 13 ionic liquids (ILs) and 25 related binary mixtures were determined at temperatures ranging from 293.15-323.15 K. The conductivity data of the pure ILs and their mixtures were fitted using the Vogel-Tammann-Fulcher (VTF) equation. The ionic association in the ILs and IL mixtures was discussed using the parameters of the VTF equation. It was demonstrated that at the same temperature, the ILs with short side chain cations, low charge density anions, and weak hydrogen bonding force between cations and anions usually exhibited high conductivity. Anions had a more obvious effect on conductivity than cations. The ionic association in