活性氧化镍电极电催化合成二甘醇酸.pdfVIP

第一届国际有机电化学与工业研讨会暨第十一届全国有机电化学与工业学术会议论文集 活性氧化镍电极电催化合成二甘醇酸 赵峰鸣，李姗姗，朱英红，马淳安‘ 浙江工业大学应用化学系，浙江杭州310014 摘要：通过电化学氧化还原技术将镍电极进行活化制各活性氧化镍电极，结合AFM、循环伏安和恒电流电解等技术 研究了二廿醇在NaOH溶液中电催化氧化合成二甘醇酸。结果表明，经活化后的镍电极对二甘醇具有较高的电催化 活性，镍电极经15rain活化处理后的电催化活性最佳。获得的最佳电解工艺条件为：电流密度17mA／cm2，电解反 二甘醇的转化率达89％。 关键词- 有机电化学；电催化；活化；二甘醇睃 of AcidonActiveNickel-·oxide Electro--catalyticSynthesisDiglycolic ElectrodeinAIkalineMedium ZHAO Shanshan，ZHU Chunan。 Fengming，LI Yinghong，MA DepatermentofAppliedChemistry，ZhqiangUniversityofTechnology,Hangzhou 310014，Zhqian吕China nickel··oxideelectrodes Abstract：Active electrochemicaloxidation—reductionexhibited preparedby electro-·catalyticactivity fortheoxidationof to in force acid alkalinemedium．Atomic diethyleneglycoldiglycolic and were to ofactive used theSlllfacecharacterizationnickel—oxidation voltammetrygalvanostaticelectrolysis study electrode resultsshowthat andelectrochemicaltowardoxidationof nickel-oxide performance diethyleneglyc01．The formedatthesurfaceofelectrodebehavesasallefficient fortheoxidationof hydroxidelayer electro—catalyst diethylene to acidinalkalinemedium．Theeffectsofvarious astimeof such activation，current glycoldiglycolic parameters density, concentrationandmedium Oiltheelectro—oxidationof were diethylen