二甲亚砜热稳定性的实验研究.pdfVIP

1 6 9 Vol . 1 6 No . 9 2 0 0 6 9 China Sa ety Science Journal Sep . 2 0 0 6 1 2 张志刚 高级工程师 钱新明 教授 ( 1 中国石油化工集团公司安全环保局, 北京 100029 2 北京理工大学爆炸科学与技术国家重点实验 , 北京 100081) :620. 30 :X937 :B 采用先进的绝热加速量热仪为手段, 对二甲亚砜的热稳定性进行了系统研究, 其内容涉 及纯二甲亚砜的热稳定性加酸碱和硫化物等杂质后二甲亚砜的热稳定性, 包括初始放热温度温升 速率温度- 压力等; 通过修正试验数据, 消除了热惰性因子的影响; 得到了二甲亚砜的热稳定性特 性研究表明, 在酸碱存在时, 二甲亚砜在 温下即可发生强烈的放热反应, 导致二甲亚砜的分解 温度提前该实验研究结果, 对二甲亚砜的安全生产工艺过程控制具有重要参考价值 二甲亚砜( DMS) ; 绝热加速量热仪; 热稳定性; 杂质; 热分解温度 Experimental Study on Thermal Stability o DMS 1 2 ZHANG Zhigang , Senior Engineer QIAN Xinming , Prof. ( 1 Bureau o Sa ety Environment Protection, SinoPec. Beijing 100029, China 2 State Key Laboratory o Explosion Science Technology , Beijing Institute o Technology , Beijing 100081, China) A stract: Thermal stability o dimethylsul oxide ( DMS) was systematically studied by advanced means o ac celerating rate calorimeter ( ARC) . The study covered the thermal stability o pure DMS, and the thermal stabil ity o DMS a ter adding acid, alkali, and sul ide impurities. The tests also included primary exothermic temper ature, temperature rising rate, and temperature via pressure etc. A ter correcting the experimental dat a, the im pact o thermal inertia actor was eliminated, and the property o thermal stability o DMS was obtained . The re sults indicated that strong exothermic reaction o DMS may happen in ambient temperature in presence o acid or alkali, and decrease the decomposition temperature o DM