氢化球磨mg-al-h粉体的显微组织及放氢特征.pdfVIP

Trans. Nonferrous Met. Soc. China 23(2013) 3112−3118 Microstructure characterization and hydrogen desorption behaviors of Mg−Al−H powders prepared by reactive milling in hydrogen 1 1,2 1 1 1 1,2 Yao WANG , Xiao-qin ZENG , Jian-xin ZOU , De-jiang LI , Xiao-mei WU , Wen-jiang DING 1. Shanghai Engineering Research Center of Magnesium Materials and Applications, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China; 2. State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China Received 3 September 2012; accepted 15 March 2013 Abstract: Microstructure and phase evolutions of Mg−Al powders ball milled in hydrogen atmosphere were investigated. Both in Mg−3%Al (mass fraction) and Mg−9%Al systems, β-MgH phase was observed upon a short milling time of 4 h and its maximum 2 content of ~80% was reached after 32 h. Neither as-milled powders of the in the two systems contain Mg17Al12. However, heating the milled powders of Mg−9%Al powders to 350 °C resulted in the precipitation of Mg17Al12. DTA/TG analyses of those powders milled for 8−40 h showed that either well-developed peak doublets or shoulders were observed, which plausibly corresponded to the separate hydrogen desorption from different particle fractions of β-MgH2 . Key words: Mg alloy; reaction milling; hydriding; nanocrystalline magnesium hydride; peak doublets