逐层丝网印刷制备TiO2纳米晶电极和其在染料敏化太阳能电池中的应用.pdfVIP

_______________________________________________________________________________ 逐层丝网印刷制备TiO 纳米晶电极及其 2 在染料敏化太阳能电池中的应用 1 1，2 1* 1 宋文哲 ，李康 ，孙岳明 ，章舒 （1.东南大学化学化工系，江苏，南京，210096 ；2.淮阴师范学院化学系，江苏，淮安，223001 ） 摘 要 用溶胶-凝胶法制备了TiO2 微粒粒径在9.7nm 左右的TiO2 溶胶，通过丝网印刷逐层 沉积到ITO 表面，TiO2 膜厚度与层数呈线性增加，易于控制。SEM 照片显示高温烧结后所 得的TiO2 纳米晶电极表面粒子直径在70nm 左右，分布均匀，孔隙较大。以TiO2 电极为工 作电极，酞菁为敏化染料，KI 0.5M/I2 0.05M 碳酸丙烯酯溶液为电解质溶液，镀银的ITO 为 对电极的染料敏化太阳能电池的最高单色光光电转化效率为 12.7％。逐层丝网印刷法适合制 作大面积TiO2 纳米晶电极，具有工业化价值。 关键词 太阳能电池；纳米晶；TiO2 ；丝网印刷；酞菁；敏化 Preparation of Nanocrystalline TiO Electrode by Layer-bye-layer 2 Screen Printing and its Application in Dye-sensitized Solar Cell 1 1,2 1* 1 Song Wenzhe ,Li Kang ,Sun Yueming ,Zhang Shu (1. Department of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu, 210096, PRC; 2. Department of Chemistry, Normal Institute of Huaiyin, Huai-an, Jiangsu, 223001, PRC) Abstract The TiO2 colloidal solution was prepared by the sol-gel method, in which the diameters of most TiO2 nanoparticulates were about 9.7nm. By layer-by-layer screen printing, TiO multilayered films were obtained. The layer-by-layer assembly of the TiO films proceeded 2 2 linearly as shown by sequential UV-vis absorption. The morphology of TiO2 nanocrystylline electrode sintered was characterized using scanning electronic microscopy and the sizes of