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DOI: 10.6023/cjoc201307055
Chinese Journal of Organic Chemistry REVIEW
N-
a b b b *,a,b *,b
(a 350108)
(b 300071)
N-, . N-
, , N-.
, P/N ,
N-,
, .
N-; ; ; ;
Recent Progress of N-Heterocyclic Carbene Complexes
Synthesized by Poly-imidazolium Salts
Lin, Caixiaa Guo, Linb Li, Qingshanb Zhang, Zhengzhib
Yuan, Yaofeng*,a,b Xu, Fengbo*,b
a
( Department of Chemistry, Fuzhou University, Fuzhou 350108)
b
( State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071)
Abstract Owing to the excellent chemical stability and catalytic activity, N-heterocyclic carbene (NHC) complexes have
always been the hotspot in the field of organic chemistry. Imidazolium salts are the precursors of NHCs, and their easy
preparation and structure diversity properties make them useful for the generation of NHC complexes with topology structures.
In this paper, the recent progress of synthesis, structure and physicochemical properties of NHC complexes with cylindrical,
cage-like, macrocyclic, square and rectangular molecular structures which are synthesized by poly-imidazolium salts is
summarized and reviewed.
Keywords N-heterocyclic carbene; poly-imidazolium salts; metal complexes; supramolecular; structure
1991 , Arduengo , NHCs
N-(N-Heterocyclic Carbenes, NHCs)[1], NHCs . NHCs
.
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