多咪唑盐合成N_杂环卡宾金属配合物及研究进展_林彩霞郭琳李庆山张正之袁耀锋徐凤波.pdf

多咪唑盐合成N_杂环卡宾金属配合物及研究进展_林彩霞郭琳李庆山张正之袁耀锋徐凤波.pdf

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DOI: 10.6023/cjoc201307055 Chinese Journal of Organic Chemistry REVIEW N- a b b b *,a,b *,b (a 350108) (b 300071) N-, . N- , , N-. , P/N , N-, , . N-; ; ; ; Recent Progress of N-Heterocyclic Carbene Complexes Synthesized by Poly-imidazolium Salts Lin, Caixiaa Guo, Linb Li, Qingshanb Zhang, Zhengzhib Yuan, Yaofeng*,a,b Xu, Fengbo*,b a ( Department of Chemistry, Fuzhou University, Fuzhou 350108) b ( State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071) Abstract Owing to the excellent chemical stability and catalytic activity, N-heterocyclic carbene (NHC) complexes have always been the hotspot in the field of organic chemistry. Imidazolium salts are the precursors of NHCs, and their easy preparation and structure diversity properties make them useful for the generation of NHC complexes with topology structures. In this paper, the recent progress of synthesis, structure and physicochemical properties of NHC complexes with cylindrical, cage-like, macrocyclic, square and rectangular molecular structures which are synthesized by poly-imidazolium salts is summarized and reviewed. Keywords N-heterocyclic carbene; poly-imidazolium salts; metal complexes; supramolecular; structure 1991 , Arduengo , NHCs N-(N-Heterocyclic Carbenes, NHCs)[1], NHCs . NHCs .

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