水焦浆水煤浆燃烧特性对比研究.pdfVIP

42 10 浙 江 大 学 学 报( ) Vol.42 o. 10 2008 10 Journal of Zhejiang University(Engineering Science) Oct. 2008 DOI: 10.3785/j.issn. 1008973X.2008. 10.028 / 赵卫东, 刘建忠, 周俊虎, 张保生, 张传名, 岑可法 ( , 310027) : , ; TGDTG ; FlynnWallOzawa . , ;, , ; , ; ,, ;,, . : ; ;; ; : TK16 : A : 1008973X(2008) Combustibility of petroleum coke water slurry compared with coal water slurry ZHAO Weidong, LIU Jianzhong, ZHOU Junhu, ZHA G Baosheng, ZHA G Chuanming, CE Kefa ( State K ey L aboratory of Clean E nergy Utiliz ation, Zhej iang Univ ersity , H angz hou 310027, China) Abstract: The ignition and combustion characteristics of petroleum coke water slurry (PCWS) were studied by thermogravimetric apparatus, and its combustibility was compared with that of the coal water slurry (CWS) samples made by Yanzhou bituminite and Guizhou anthracite. T he ignition temperature was ob tained by TGDTG method and the reaction kinetics was analyzed with FlynnWallOzawa method. Results show that the ignition and burnout temperatures of PCWS are larger than Yanzhou bituminite CWS, while smaller than Guizhou anthracite CWS; the ignition and burnout temperatures grow higher as the heating rates become larger, which means the combustion process transfers to ahighertemperaturezone; the inte gration index becomes larger, which indicates the combustibility turns better. The dynamic analysis shows that the activation energy of PCWS is lower than that of Yanzhou bituminite CWS and Guizhou anthracite CWS at a certain conversion rate; the PCWS has the characteristic of being difficult to light while burning tempestuously once it is ignited. Key words: petroleum coke water slurry ( PCWS) ; coal water slurry (CWS) ; thermogravimetry; combus tibility; d