白芍和黄连中十五种有机氯和拟除虫菊酯类农药的多残留分析方法.pdfVIP

2006, 8( 1): 65-70 Ch inese Journal of Pesticide Science 研究论文 * 吴加伦 , 邹耀华, 李丽青 ( , 10029) : 建立了白芍和黄连两种中药材中六六六滴滴涕艾氏剂五氯硝基苯甲氰菊酯氯菊酯 氯氰菊酯氰戊菊酯溴氰菊酯等 药的多残留气相色谱分析方法在索氏提取器中以石油醚( 60 ~ 90 )为溶剂提取样品, 提取液经氧化铝与弗罗里硅土的混合柱净化, 采用 残分析专用柱 残 柱分离, GC-ECD 检测器检测 药的残留量方法的最小检出量( LOD)为 0. 000 5~ 0. 006 0 ng, 最低检测浓度( LOQ ) 为 0. 005 ~ 0. 050 mg /kg; 个添加水平 药的平均回收率为79. 8% ~ 114. 6% , 相对标准偏差(RSD )均小于 10% (n = 6) : 中药材; 白芍; 黄连; 有机氯; 拟除虫菊酯; 药多残留分析 : O65771 : A : 1008-7 0 ( 2006) 01- 0065- 06 M ult-i residue Analysis of Fifteen Organochlorine and Pyrethroid Insecticides inR a id ix p a eon ia e A lba andRh izoma cop tid is * W U Jia-lun , ZOU Y ao-hua, LI L -i qing ( Institute of Pesticide and Environm ental Toxicology, Zhejiang Un iversity, H angzhou 10029, C hina ) Abstract: A m ethod for rap id determ ination of fifteen organochlorine and pyrethroid insecticide residues ( included -HCH, -HCH, -HCH, -HCH, p, p -DDE, o, p -DDT, p, p -DDD, p, p -DDT, PCNB, aldrin, fenpropathrin, perm ethrin, cypermethrin, fenvalerate, deltam ethrin) in tw o kinds of Ch inese crude drugs (Raid ix paeon iae A lba andRh izoma coptid is) w ere developed. The samp le w as extracted in Soxhlet w ith petroleum ether ( 60 ~ 90C ) and cleaned up w ith the m ixture of alum inum oxide-florisil ( 5 g and 7 g), detected by GC-ECD. The lmi it of detection ( LOD ) of 15 organochlorine and pyrethroid insecticidesw ere 0. 000 5 ~ 0. 006 0 ng, and the lmi it of quantitation ( LOQ) of the m ethod for 15 organochlorine and pyrethro id insecticides inRaidix paeon iae A lba andRh izoma coptidis w ere 0. 005~ 0. 050m g /kg, and fortified recovery of pe