正戊烷异构化催化剂改性的研究论文.doc

XX大学 工程硕士专业学位论文 论文题目： 正戊烷异构化催化剂改性研究 硕 士 生： 指导教师： 教 授 工程领域： Thesis for the Master Degree in Engineering Study on catalyst modification for n-pentane isomerization Candidate: Zhang Yibin Tutor: Yu Tao Specialty: Chemical Engineering Date of oral examination: 9th June. 2012 University: Northeast Petroleum University 正戊烷异构化催化剂改性研究 摘要正戊烷催化剂评价的反应介质，10mL连续流动式固定床高压微反-色谱联合装置对催化剂进行评价。Ni金属活性组分，丝光沸石（M）为载体，制备Ni/HM催化剂酸洗、铵交换次数、竞争吸附剂、铵焙烧温度、镍含量、镍焙烧温度、催化剂还原温度以及反应条件对催化剂反应性能的影响。用氟硅酸铵磷酸氯化铝对NiHM进行改性，通过对异构化催化剂评价与筛选，实验结果表明随镍金属含量的增催化剂异构化活性，当镍金属含量一定值时，，说明金属的加脱氢功能不再是反应的控制步骤。随氟含量增加，明显提高Ni-F/HM催化剂的异构化活性，反应温正戊烷异构化遵循双功能催化反应机理，金属与酸功能的良好匹配是异构化催化剂研究的关键。制备的Ni-F/HM催化剂Ni含量为4%，F含量为5%，总孔容为0.2382mL/g，平面孔半径1.0884nm，催化剂的比表面积为327.63/g，反应性能最佳。T=260℃，P=MPa，WHSV=h-1，H2/nC5=4:1，正戊烷转化率为71.36%，异戊烷收率为68.2%，异戊烷选择性为95.3%，液体产物收率为96.85%。关键词：正戊烷异构化丝光沸石催化剂 Study on catalyst modification for n-pentane isomerization ABSTRACT Select n-pentane as reaction medium to evaluate catalyst in experiment. It has evaluated on the experiment set-up composed of high pressure microreactor used 10 mL continous flow fixed-bed and of chromatography unit. For isomerization of n-pentane over mordenite, Ni/HM catalyst was prepared with Ni as active component. The effects of acid washing, the number of ammine exchanged, addition of competitive absorbate, content of ammonia, temperature for calcinations ammonia, content of Ni, temperature of calcinations Ni, temperature of catalyst reduction and reaction conditions on catalyst are respectively investigated. Then, improved isomerization function of Ni/HM catalyst with ammonium fluorosilicate, ammonium fluorinate and aluminium chloride. According to the evaluate and the sift through light paraffine isomerization catalyst, it determines the best performance. Besides, it uses orthogonal experiment method for determining the optimum rea