Rational design, synthesis of reaction-based dual-channel cyanide sensor in aqueous solution》.pdf

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 152 (2016) 288–293 Contents lists available at ScienceDirect Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy journal homepage: www.else /locate/saa Rational design, synthesis of reaction-based dual-channel cyanide sensor in aqueous solution Jun-Jian Li, Wei Wei, Xiao-Liang Qi, Xiao Xu, Yu-Cheng Liu, Qiu-Han Lin ⇑, Wei Dong ⇑ School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China h i g h l i g h t s g r a p h i c a l a b s t r a c t A highly selective and sensitive cyanide ion sensor. Fluorescent ‘‘turn on’’ response CN with detection limit as 1.8 107 mol/L. The sensor L recognizes CN selectively in aqueous solution. a r t i c l e i n f o a b s t r a c t Article history: A new dual-channel sensor for the detection of cyanide was developed based on the conjugated of naph- Received 22 March 2015 thalene and malononitrile. Upon the addition of CN, the sensor displayed very large blue-shift in both Received in revised form 28 May 2015 fluorescence (80 nm) and absorption (120 nm) spectra. The sensor of cyanide was performed via the Accepted 23 July 2015 nucleophilic attack of cyanide anion to vinylic groups of the sensor with a 1:1 binding stoichiometry Available online 26 July 2015 and the color changed of the sensor is mainly due to the intramolecular cha