Reaction pathway and kinetics of C3–C7 olefin transformation over high-silicon HZSM-5 zeolite at 400–490 °C》.pdf

Chemical Engineering Journal 280 (2015) 222–232 Contents lists available at ScienceDirect Chemical Engineering Journal journal homepage: www.else /locate/cej Reaction pathway and kinetics of C –C olefin transformation 3 7 over high-silicon HZSM-5 zeolite at 400–490 C Xun Huang, Dilireba Aihemaitijiang, Wen-De Xiao ⇑ School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, PR China h i g h l i g h t s Heptene dominantly cracks into equimolar butene and propylene. Hexene and pentene convert through both mono- and bi-molecular cracking. Butene and propylene mainly takes place in bi- and tri-molecular cracking, respectively. The rate of bi- and tri-molecular cracking decreases with temperature. a r t i c l e i n f o a b s t r a c t Article history: The pathway and kinetics of C –C olefin transformation reactions were investigated in a fixed-bed reac- 3 7 Received 12 February 2015 tor over a high-silicon HZSM-5 catalyst at 400–490 C in this work. The main reaction pathway was iden- Received in revised form 28 May 2015 tified on the observations of the product distribution when the individual olefin was fed alone. The results Accepted 30 May 2015 = = = show that C7 proceeds