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Reduction of hexachloroplatinate(IV) ions with methanol under UV radiation》.pdf
Journal of Photochemistry and Photobiology A: Chemistry 314 (2016) 133–142
Contents lists available at ScienceDirect
Journal of Photochemistry and Photobiology A:
Chemistry
journal homepa ge: www.elsev /locate/jphotochem
Reduction of hexachloroplatinate(IV) ions with methanol under UV
radiation
a b,*
Marek Wojnicki , Przemysław Kwolek
aAGH University of Science and Technology, Faculty of Non-Ferrous Metals, al. A. Mickiewicza 30, 30-059 Krakow, Poland
b Department of Materials Science, Rzeszow University of Technology, ul. W. Pola 2, 35-959 Rzeszów, Poland
A R T I C L E I N F O A B S T R A C T
Article history: The aim of presented study was the detailed spectroscopic characterization of the mechanism of the
Received 26 May 2015 photoreduction of hexachloroplatinate(IV) with methanol. The reaction mixture was illuminated at
Received in revised form 18 August 2015 375 nm and it was shown that PtCl62 ions were reduced with methanol to PtCl42 only in the presence of
Accepted 22 August 2015
light. In the dark, methanol did not reduce hexachloroplatinate(IV) at the room temperature.
Available online 25 August 2015 2
Formaldehyde was the main product of methanol oxidation. Subsequently, PtCl4 ions were
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