M（M=Sm，Nd，Pr）替代La对A2B7型贮氢合金电化学性能的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 24(2014) 4012−4022 Effects of substituting La with M (M=Sm, Nd, Pr) on electrochemical hydrogen storage characteristics of A B -type electrode alloys 2 7 Yang-huan ZHANG 1,2 1 2 2 2 2 , Peng-xin LI , Tai YANG , Ting-ting ZHAI , Ze-ming YUAN , Shi-hai GUO 1. Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China; 2. Department of Functional Material Research, Central Iron and Steel Research Institute, Beijing 100081, China Received 31 March 2014; accepted 16 August 2014 Abstract: The partial substitution of M (M=Sm, Nd, Pr) for La was performed in order to ameliorate the electrochemical hydrogen storage performance of RE–Mg–Ni-based A B -type electrode alloys. The La M Mg Ni Al Si (M=Sm, Nd, Pr; x =0−0.4) 2 7 0.8–x x 0.2 3.35 0.1 0.05 electrode alloys were fabricated by casting and annealing and their microstructures were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The major phases (La, Mg) Ni with the hexagonal Ce Ni -type structure and LaNi with 2 7 2 7 5 the hexagonal CaCu -type structure make up the basic microstructure of the experimental alloys. The discharge capacities