Ni含量对提高Zn-Ni合金在3.5%NaCl溶液中耐腐蚀性能的影响（I）极化和阻抗研究.pdfVIP

Trans. Nonferrous Met. Soc. China 25(2015) 2807−2816 Role of Ni content in improvement of corrosion resistance of Zn−Ni alloy in 3.5% NaCl solution. Part I: Polarization and impedance studies Hany M. ABD EL-LATEEF, Abdel-Rahman EL-SAYED, Hossnia S. MOHRAN Chemistry Department, Faculty of Science Sohag, Sohag University, Sohag 82524, Egypt Received 9 October 2014; accepted 19 January 2015 Abstract: Zn plays an important role in the protection of iron and steel from corrosion in sea water, and the alloying of Zn and Ni can improve its corrosion resistance. The corrosion behavior of Zn−Ni alloys in synthetic sea water (3.5% NaCl, mass fraction) was studied using Tafel plot and electrochemical impedance spectroscopy (EIS) techniques. The corrosion resistance of the investigated alloys with various Ni contents (0.5%−10%, mass fraction) was compared with that of Zn. The results show that the corrosion resistance of Zn−Ni alloys (except 0.5% Ni) is superior to that of Zn. The 10% Ni gives the highest corrosion resistance due to the formation of γ-Zn3Ni with γ-ZnNi phases in the alloy. In the case of alloy I (0.5% Ni), it exhibits a higher corrosion rate (less corrosion resistance) than Zn. Key words: Zn−Ni alloy; Ni content; corrosion resistance; Cl− ions; impedance; polarization coatings because of their higher degree of corrosion 1 Introduction resistance to NaCl in the atmospheric environment [8]. Zn−Ni alloys have been widely used in the trades of ship Zn has be