聚丁二酸丁二酯乳酸共混材料的结构与性能.pdfVIP

面粘结得以增强，相形态显著改善；尽管两组分自身以及彼此间会发生轻度的交联和接枝 反应，但该反应并不会破坏PBS和PLA本身的大分子链结构；与未增容的体系相比，界 面张力的减小和界面层的增厚导致增容体系抗冲强度和拉伸强度全面提升；此外，DCP的 变温度彼此靠近，但结晶能力却都有所下降。 关键词：聚丁二酸丁二酯；聚乳酸；共混物；相形态；结构流变学 n IIlll I llIll IllllI l tl III Y2257982 Abstract As suchas biodegradablepolymermaterials，thermoplasticaliphaticpolyesters typical interest in poly(butylenesuccinate)(PBS)andpolylactide(PLA)havegeneratedgreat recently field．PBSwith thermal andslow thematerialresearch toughness，highstability high showslow PLAwith andfast rateshows rate strength，whilehighstrength degradation poor and thermal blendthem isaconvenient toughnesspoor stability．Therefore，totogether strategy new materialswith duetotheir toobtain biodegradable highperformance property two are complementarity．Howeverthepolymercomponentsincompatible andthe interfaceadhesionrestrainsthe ontheirblends．To poor propertyimprovement design andtofabricate blends晰thexcellent ishence biodegradablepolymer performance，itnecessary to the andtoestablishtherelationbetween aspectsinfluencingphasemorphology phase explore structureand ofPBS／PLAblends． performance Inthis PBS／PLAblendswithvarious ratiosand ratios work，therefore，the blending viscosity were